Step 1: Open Dreamweaver and go to the "Sites" menu and click "New Site".
Step 2: Enter the Site Name (this is just to keep track of projects) and the local folder you wish to store the site files.
Step 3: Next Click Servers, then click the plus icon to add a new server and enter your FTP information and click save.
Step 4: Click the sync icon normally located in the bottom right hand corner of the screen.
Step 5: Click Preview
Step 6: Check the files that will be synced. If everything looks alright, click OK.